Dynasty Warriors 6 - Shu Kingdom Character

 Ma Chao :

Complete battle objective 2, Battle of Hanzhong (Wei)

Zhao Yun :

Initially Available.

 Guan Yu :

Initially Available.

Zhang Fei :

Initially Available.

 Liu Bei :

Clear musou mode with three Shu officers.

 Zhuge Liang :

Clear musou mode with one Shu officer.

Huang Zhong :

Complete battle objective 1, Battle of Mt. Ding Jun (Wei)

Wei Yan :

Complete battle objective 2, Battle of Wu Zhang Plains (Shu)

 Guan Ping :

Complete battle objective 2, Battle of Fan Castle (Shu)

Pang Tong :

Complete battle objective 3, Battle of Cheng Du (Shu)

Yue Ying :

Complete battle objective 1, Battle of Wu Zhang Plains (Wei)